By Dennis W. Smith, Scott T. Iacono, Dylan J. Boday, Sharon C. Kettwick
content material: PREFACE ; 1. THE kingdom OF FLUOROPOLYMERS ; DYLAN J. BODAY ; 2. contemporary ADVANCES IN in part FLUORINATED ARYLENE VINYLENE ETHER (FAVE) ; POLYMERS ; SHARON C. KETTWICH, BENJAMIN R. LUND, DENNIS W. SMITH JR., AND SCOTT T. IACONO ; three. SYNTHESIS AND CHARACTERIZATION OF SEMI-FLUORINATED POLYARYLENE ; COPOLYMERS ; STEPHEN M. BUDY AND DOUGLAS A. LOY ; four. in the direction of steel MEDIATED RADICAL POLYMERIZATION OF VINYLIDENE FLUORIDE ; ALEXANDRU D. ASANDEI, CHRISTOPHER P. SIMPSON, OLUMIDE I. ADEBOLU, AND ; YANHUI CHEN ; five. WELL-DEFINED FLUORINE-CONTAINING big name POLYMERS OF VINYL ETHERS: ; PRECISION SYNTHESIS by way of BASE-ASSISTING residing CATIONIC POLYMERIZATION AND ; THERMORESPONSIVE SOLUBILITY TRANSITIONS ; SHOKYOKU KANAOKA, HIROAKI SHIMOMOTO, DAI FUKAMI, AND SADAHITO AOSHIMA ; 6. SEMI-FLUORINATED POLYMER/POSS skinny motion pictures NANOCOMPOSITES: reaction TO ; WATER ; DVORA PERAHIA, DILRU R. RATNAWEERA, UMESH M. SHRESTHA, SCOTT T. IACONO, ; DENNIS W. SMITH, JOSEPH MABRY, AND JAROSLAW MAJEWSKI ; 7. FUNCTIONALIZATION OF FLUOROALKYL POLYHEDRAL OLIGOMERIC SILSESQUIOXANES ; (F-POSS) ; SEAN M. RAMIREZ, YVONNE J. DIAZ, RAYMOND CAMPOS, TIMOTHY S. HADDAD, AND ; JOSEPH M. MABRY ; eight. the facility OF PERFLUORINATED AMPHIPHILIC POLYMERS AT INTERFACES ; F. E. GOLLING, T. SCHUSTER, C. GEIDEL, L. MAMMEN, D. VOLLMER, ok. MULLEN, AND ; M. KLAPPER ; nine. FLUORINATED POLYMERS AS OXIDIZERS FOR full of life COMPOSITES ; CHRISTOPHER A. CROUSE ; 10. fresh ADVANCES ON NEW FLUORINATED COPOLYMERS in response to CARBONATE AND ; OLIGO(ETHYLENE OXIDE) by way of RADICAL COPOLYMERIZATION ; ALI ALAAEDDINE, CLAIRE NEGRELL, AND BRUNO AMEDURI ; eleven. SUPEROLEOPHOBIC SURFACES ; ARUN okay. KOTA AND ANISH TUTEJA ; 12. 2D-NMR experiences OF POLYVINYLIDENE FLUORIDE ; ERIC B. TWUM, XIAOHONG LI, ELIZABETH F. MCCORD, PETER A. FOX, DONALD F. LYONS, ; AND PETER L. RINALDI ; EDITORS>' BIOGRAPHIES ; INDEXES ; writer INDEX ; topic INDEX
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Smith, D. , Jr. High Perform. Polym. 2007, 581. Iacono, S. ; Budy, S. ; Moody, J. ; Smith, R. ; Smith, D. , Jr. Macromolecules 2008, 41, 7490. ; Iacono, S. ; Budy, S. ; Dennis, A. ; Smith, D. ; Smith, R. C. J. Mater. Chem. 2008, 18, 1970. Tackett, K. ; Iacono, S. ; Smith, D. , Jr. Polym. Prepr. 2008, 49, 01. Gilliard, R. ; Iacono, S. ; Budy, S. ; Moody, J. ; Smith, D. ; Smith, R. C. Sens. Actuators, B 2009, 143, 1. Moody, J. ; Smith, D. ; Iacono, S. T. Org. Biomol. Chem. 2011, 9, 4842. Feiring, A.
A recent consolidated accounts reports the details of these PFCP polymers (27). Spectroscopic analyses of the crude reaction mixtures show that these polymerizations are very clean with no byproducts or branching. Further, spectroscopic data do not show the presence of any chiral carbons as typically seen in FAVE and PFCB chemistry. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2012. ch002 via a double addition-elimination mechanism. While FAVE polymers form fluoroalkanes in the presence of electrophilic H+ (Cs2CO3 as base), PFCP polymers show no such behavior under similar conditions (TEA as a base).
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Advances in Fluorine-Containing Polymers by Dennis W. Smith, Scott T. Iacono, Dylan J. Boday, Sharon C. Kettwick